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11-Phenyl-7,8,9,10,10a,11,12,13,14,15-deca­hydro-5H-3,1-benzoxazino[2,1-e]acridine

✍ Scribed by Kaminskiia, Vladimir A. ;Slabkoa, Oleg Yu. ;Kachanova, Andrey V. ;Gerasimenko, Andrey V. ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
155 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

2,7

]tridecan-13-one reacts with 2-aminobenzyl alcohol to form the title compound, C 26 H 29 NO, which crystallizes with two independent molecules in the asymmetric unit. The N atom shows a nearly planar coordination owing to the strain imposed on the fused-ring compound.

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10-Methyl-8,9,10,11,11a,12-hexa­hydro-5H
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✍ Lena, Gersande ;Wenger, Emmanuel ;Guichard, Gilles ;Didierjean, Claude 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 245 KB

In the title compound, C 13 H 15 N 3 O 2 , the triazepane ring adopts a twist-boat conformation and the piperidine ring adopts a boat conformation. The molecular packing is stabilized by N-HÁ Á ÁO, C-HÁ Á ÁO, C-HÁ Á Á and van der Waals interactions.

9-(4-Hydroxy-3-methyoxy­phenyl)-3,3,6,6,
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✍ Tu, Shu-Jiang ;Zhang, Xiao-Jing ;Zhu, Song-Lei 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 164 KB

Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.042 wR factor = 0.108 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis(μ-18-nitro-2,3,5,6,8,9,11,12,14,15-d
Bis(μ-18-nitro-2,3,5,6,8,9,11,12,14,15-deca­hydro-1,4,7,10,13,16-benzohexaoxacyclo­octa­decine)bis[(chloro­chromato)potassium]
✍ Kotlyar, Sergei A. ;Shishkina, Svetlana V. ;Shishkin, Oleg V. ;Pluzhnik-Gladyr, 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 211 KB

In the title dimeric structure, [K 2 (C 16 H 23 NO 8 ) 2 {CrClO 3 } 2 ], the two macrocyclic ligands are oriented head-to-head with the stacked nitrobenzene groups.