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4,5-Bis(benzylthio)-1,3-dithiole-2-thione compounds: crystal structures of [(p-XC6H4CH2)(p-XC6H4CH2)dmit: X=Y=OMe; X=Y=NO2; and X=OMe, Y=NO2]

✍ Scribed by Zahid H. Chohan; R. Alan Howie; James L. Wardell; Solange M.S.V. Wardell


Book ID
110275839
Publisher
Springer
Year
1999
Tongue
English
Weight
110 KB
Volume
29
Category
Article
ISSN
1572-8854

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The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho