The title compound, C 8 H 4 S 2 8 Á2Cl À , was prepared electrochemically. To our knowledge, it is the ®rst dication salt of tris(methylenedithio)tetrathiafulvalene (BMDT-TTF). The asymmetric unit consists of two chloride anions and one dication, all three located on mirror planes. In the crystal st
4,4',5,5'-Tetrakis(methylsulfanyl)tetrathiafulvalene
✍ Scribed by Wang, Lei ;Zhang, Jing-Ping ;Zhang, Bin
- Book ID
- 104483110
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 230 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 10 H 12 S 8 , crystallizes in a monoclinic space group with one molecule in the asymmetric unit. All bond lengths and angles in the molecule are normal. The crystal packing is stabilized by van der Waals forces.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê Disorder in main residue R factor = 0.040 wR factor = 0.060 Data-to-parameter ratio = 15.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Tetramethyltetrathiafulvalene and 1,4-dinitrobenzene co-crystallize in a mixed-stack 1:1 complex, C 10 H 12 S 4 ÁC 6 H 4 N 2 O 4 , without appreciable charge transfer. Both molecules lie on the same crystallographic twofold axis.
The title compound, C 16 H 13 BrOS, was prepared by the Lewis acid-catalysed reaction of 4 0 -bromo-1,1 0 -biphenyl-4-ol withchloro--(methylsulfanyl)acetone. The crystal structure is stabilized by a C-HÁ Á Á interaction involving a CH group of the 4-bromophenyl ring and the furan ring.
The centrosymmetric title compound, C 54 H 70 O 4 , contains a benzene ring at the centre and four 2-tert-butyl-4-methylphenoxymethyl substituents. In the structure of the molecule, some of the benzene rings are coplanar. The title compound displays intramolecular CÐHÁ Á ÁO hydrogen bonds. The cryst