In the title compound, C 18 H 33 N 3 Si 2 , the central diketiminate system is essentially planar. A short intramolecular hydrogen bond involving the imine N atoms forms a pseudo-sixmembered ring.
{4,4′-Di-tert-butyl-6,6′-bis(dimethoxymethyl)-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]bis(thiophenolato)-κ4S,N,N′,S′}nickel(II)
✍ Scribed by Bjernemose, Jens K. ;McKenzie, Christine J. ;Raithby, Paul R. ;Teat, Simon J.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 375 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal synchrotron study T = 150 K Mean '(C±C) = 0.004 A Ê R factor = 0.084 wR factor = 0.228 Data-to-parameter ratio = 53.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
In the title compound, [Ni(C 26 H 28 N 2 O 2 S 2 )], the three independent Ni II complex cations are conformational isomers. The Ni atom has a square-planar environment and is coordinated by two imine functions and two S atoms. The NiÐN and NiÐS bond lengths are in the ranges 1.893 (4)± 1.909 (4) an
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.069 wR factor = 0.205 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.