4,4′-Bipyridyl–2-chloro-4-nitrobenzoic acid (1/2)
✍ Scribed by Gotoh, Kazuma ;Ishida, Hiroyuki
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 480 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the crystal structure of the title 1:2 cocrystal, C~10~H~8~N~2~·2C~7~H~4~ClNO~4~, the two components are held together by short O—H...N hydrogen bonds. The pyridine rings of the bipyridyl molecule are twisted by 27.90 (5)° with respect to each other. The 1:2 units are connected by C—H...O hydrogen bonds, forming a centrosymmetric supramolecular ring.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 300 K Mean '(C±C) = 0.004 A Ê R factor = 0.051 wR factor = 0.119 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title hydrated molecular salt, C~12~H~14~N~2~ ^+^·2C~7~H~4~NO~4~ ^−^·2H~2~O, the complete cation is generated by a crystallographic twofold axis running perpendicular to the central C—C bond. The components give rise to an infinite three-dimensional framework __via__ intermolecular N—H...O an