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4,4′-Bipyridinium tetra­chloridopalladate(II)

✍ Scribed by Valdés-Martínez, Jesús ;Toscano, Rubén A. ;Germán-Acacio, Juan Manuel

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
82 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, (C~10~H~10~N~2~)[PdCl~4~], the Pd atom in the tetrachloridopalladate anion exhibits a square-planar geometry. The anion is hydrogen bonded to the bipyridinium cation by an N—H...Cl hydrogen bond to form chains. The bipyridinium cation and the tetrachloridopalladate anion exhibit perfect 2/m symmetry with the Pd atom located on a 2/m symmetry site.

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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.034 wR factor = 0.090 Data-to-parameter ratio = 11.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.