[4+2]- and [2+4]-cycloaddition processes of 4,5-dicyanopyridazine with 2,3-dimethylbuta-1,3-diene
β Scribed by Rodolfo Nesi; Donatella Giomi; Stefania Turchi; Paola Paoli
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 390 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
β¦ Synopsis
Ababwck The title compnds afforded under mlathly mild conditions the polycyclic systems 3% 4, and 5 thmugb altemative collwmitant cycloadditions; the mactivily ofthe wdazinc syxtem wascri~innucnccdbythepnsavxofmcthyl~atthc3and6~ti~.Thesllctond3r andthestenochemistryofswemestablishedbyx-ray-.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
On irradiation (350 nm) in the presence of 2,3-dimethylbuta-1,3-diene (8), 4-(alk-1-ynyl)coumarins 1 afford mixtures of cyclobuta-and cycloocta-annulated products 9 and 10, respectively. In contrast, the corresponding thiocoumarins 2 react with the same diene chemoselectively to give cyclohexa-annul