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(4-tert-Butyl-2-methyl­thio­semicarb­azido)(O-methyl­di­thio­phosphato)­palladium(II)

✍ Scribed by Janča, Michal ;Taraba, Jan ;Příhoda, Jıří

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
227 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title Pd complex, [Pd(C 6 H 14 N 3 S)(CH 3 O 2 PS 2 )], is formed from Pd(acetate) 2 and 5-tert-butylamino-4-methyl-2-sul®do-2thioxo-1,3,4,2! 5 -thiadiazaphospholan-5-onium, (1), in methanol. The Pd atom is coordinated to two different ligands which are generated in situ as a result of methanolysis of the starting compound (1). Thus, Pd is complexed by the O-methyldithiophosphate ligand and by 2-methyl-4-tert-butylthiosemicarbazide. Two molecules of the Pd chelate are linked by two intermolecular NÐHÁ Á ÁO hydrogen bonds, the NÁ Á ÁO distances of which are 3.361 and 2.827 A Ê .

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✍ Bjernemose, Jens K. ;McKenzie, Christine J. ;Raithby, Paul R. ;Teat, Simon J. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 375 KB

Single-crystal synchrotron study T = 150 K Mean '(C±C) = 0.004 A Ê R factor = 0.084 wR factor = 0.228 Data-to-parameter ratio = 53.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.