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4-Substituted Piperidines. II. Reaction of 1-Benzyl-4-cyano-4-t-aminopiperidines with Organometallic Compounds

✍ Scribed by Hermans, Bert; Van Daele, Paul; Van De Westeringh, Cornelis; Van Der Eycken, Cyriel; Boey, Jozef; Janssen, Paul A. J.


Book ID
121315318
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
555 KB
Volume
8
Category
Article
ISSN
0022-2623

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✍ Dan-Mei Dai; You-Cheng Liu; Jing Li 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 411 KB

## Abstract The photoinduced reaction of a mixture of (Z)‐α‐cyano‐β‐bromomethylcinnamide (1) and (__E__)‐α‐cyano‐β‐bromomethylcinnamide (2) with 1‐benzyl‐1, 4‐dihydronicotinamide produces a mixture of the (__E__)‐ and (__Z__)‐ isomers of α‐cyano‐β‐methylcinnamide (3 and 4). Using spin‐trapping tech