4-Spiro[2.n]alkyl Cations and Their Rearrangements
β Scribed by G. K. Surya Prakash, Alex P. Fung, George A. Olah and Tarik N. Rawdah
- Book ID
- 123634492
- Publisher
- National Academy of Sciences
- Year
- 1987
- Tongue
- English
- Weight
- 618 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0027-8424
- DOI
- 10.2307/29981
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π SIMILAR VOLUMES
In a recent paper' we reported the synthesis of the first representative of a spirally connected adamantane-homoadamantane molecule (I).
H. C. Brown and G. Ham, J.Am. Chem,Soc, && 2735 (1956) found a cyclopentyl/ cyclohexyl rate ratio of 14. Cyclobutyl tosylate is 11 timae as reactive as cyclohexyl tosylate.' Correcting for the 7OO:l ratio found with I and III, one obtains a rate acceleration of 8X10' for cyclobutyl tosylate.
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