𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Cationic rearrangements of spiro[adamantane-2,4′-homoadamantan-5′-ol]

✍ Scribed by E. Boelema; Hans Wynberg; J. Strating


Book ID
104248255
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
171 KB
Volume
12
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


In a recent paper' we reported the synthesis of the first representative of a spirally connected adamantane-homoadamantane molecule (I).


📜 SIMILAR VOLUMES


Solvolytic hydroperoxide rearrangements
✍ Robert C. Ronald; Suzanne M. Ruder; Thomas S. Lillie 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 276 KB

Rearrangement of spiro octan-4-01, 1, in acidified THF-H202 is a selective process in which substitution occurs with retention of configuration and ring-expansion with inversion of the carbinyl center. Recently, we reported that rearrangements of certain cyclopropyl carbinols in acidified 90% H202-

Preparation of 2,4,5-triarylimidazol-4-o
✍ Gonghao Lu; Akira Katoh; Zhiqiang Zhang; Zhizhi Hu; Peng Lei; Masaru Kimura 📂 Article 📅 2010 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 720 KB

## Abstract magnified image Lophine hydroperoxides underwent base‐triggered 1,5‐phenyl migration in DMSO to afford imidazolones in high yields, instead of amidines with chemiluminescence (CL). The corresponding imidazolols were believed to intermediates and they were successfully obtained by treati

The Adamantane Rearrangement of Tricyclo
✍ Kanai L. Ghatak; Camille Ganter 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 345 KB 👁 1 views

Regioselective generation of the C(2)-carbocation a of tricyc10[4.2.2.0',~]decane (1) by treatment of both corresponding epimeric alcohols 5 and 6 with BF, and trapping the rearranged tricy~lo[S.3.0.O~~~]decan-7-yl carhocation b with Et,SiH as hydride-ion donor (ionic hydrogenation) gives the corres

Photochemical rearrangements of cross-co
✍ Paul J. Kropp; William F. Erman 📂 Article 📅 1963 🏛 Elsevier Science 🌐 French ⚖ 237 KB

IT is well established that 4-ntethylcyclohexadienones of the santonin type undergo photochemical transformation in aqueous acetic acid to perhydroasulene derivatives of the isophotosantonic la&one type.' The photochemical properties of cyclohexadienones which are unsubstituted at C4 have also been