Rearrangement of spiro octan-4-01, 1, in acidified THF-H202 is a selective process in which substitution occurs with retention of configuration and ring-expansion with inversion of the carbinyl center. Recently, we reported that rearrangements of certain cyclopropyl carbinols in acidified 90% H202-
Cationic rearrangements of spiro[adamantane-2,4′-homoadamantan-5′-ol]
✍ Scribed by E. Boelema; Hans Wynberg; J. Strating
- Book ID
- 104248255
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 171 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
In a recent paper' we reported the synthesis of the first representative of a spirally connected adamantane-homoadamantane molecule (I).
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