4-[N,N-Bis(2-cyanoethyl)amino]pyridinium perchlorate
✍ Scribed by Geng, Jin-Long ;Ni, Jun ;Liu, Rui ;Chen, Hui-Lan ;Wang, Zhi-Lin
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 179 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.049 wR factor = 0.118 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
In (C 11 H 12 N 4 ) 2 ZnCl 2 , the zinc(II) center is coordinated by the pyridine nitrogen atoms of two 4-[N,N-bis(2-cyanoethyl)amino]pyridine ligands and two chlorine atoms in a tetrahedral geometry.
Diaminopropane-j 2 N,N 0 0 0 )[tris(2-aminoethyl)amine-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]nickel(II) bis(perchlorate)
In the title compound, C 13 H 15 N 3 O 2 S, the geometric parameters are in the normal ranges. The amide N atom is coordinated in an almost trigonal-planar fashion.
The asymmetric unit of the title complex, [Ni(C~11~H~29~N~5~)](ClO~4~)~2~, consists of an [Ni(C~11~H~29~N~5~)]^2+^ cation and two uncoordinated perchlorate anions. The Ni^II^ atom is five-coordinated in a slightly distorted square-pyramidal geometry, with four of the N atoms forming the basal plane