## Abstract Fused tricyclic 7‐phenyl‐5__H__‐thizolo[5,4‐__e__]pyrrolo[1,2‐__a__][1,4]diazepin‐10(9__H__)one (**10**) was prepared by thermolysis of 2‐phenyl‐4‐(1‐pyrrolylmethyl)thiazole‐5‐carbonyl azide (**9**) in acetic acid. In addition, starting from **10**, 7‐phenyl‐5__H__‐thiazolo [5,4‐__e__][
4-Furoyl-2,3,4,5,6,7-hexahydro-r-2,c-7-diphenyl-1H-1,4-diazepin-5-one: supramolecular aggregation through C—H⋯O interactions
✍ Scribed by Thamotharan, S. ;Parthasarathi, V. ;Muthukumar, M. ;Thanikasalam, K. ;Jeyaraman, R. ;Linden, Anthony
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 316 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 22 H 20 N 2 O 3 , the phenyl substituents adopt equatorial orientations. The seven-membered heterocyclic ring adopts a distorted chair conformation. In the solid state, the symmetry-related molecules are linked by intermolecular CÐHÁ Á ÁO hydrogen bonds to form a supramolecular aggregation.
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