In the title compound, C~15~H~12~ClNOS, the thiazolidine ring adopts a twist conformation, with the S and adjacent C (bearing chlorophenyl) atom deviating by −0.140 (1) and 0.158 (2) Å, respectively, from the plane through the other three ring atoms.
(4-Chloromethyl-4-hydroxy-3-phenylthiazolidin-2-ylidene)ammonium chloride acetone solvate
✍ Scribed by Crane, Jonathan D. ;Sparke, Amanda E.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 335 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C 12 H 13 N 3 OS, the molecular backbone formed by the thiazolidinone and 2-(propan-2-ylidene)hydrazone groups is planar. There are some weak intra-and intermolecular hydrogen-bond interactions which stabilize the crystal structure.
The title compound, C 18 H 14 F 4 N 2 O 2 SÁCHCl 3 , forms a onedimensional hydrogen-bonded chain via a single O-HÁ Á ÁN interaction; the chain runs approximately along the [110] axis. The two benzene rings are almost parallel to one another, forming a dihedral angle of 8.43 (8) .
In the title structure, C 24 H 17 N 2 O 2 S + ÁBr À ÁCH 3 OH, the cations, anions and solvent molecules form centrosymmetric clusters via a combination of intermolecular N-HÁ Á ÁO, O-HÁ Á ÁBr and C-HÁ Á ÁBr interactions.