The title compound, C 15 H 17 NO 2 S, crystallizes with two independent molecules in the asymmetric unit. The molecules are linked into dimers via N-HÁ Á ÁO hydrogen bonds.
4-Chloro-N-(2,4-dimethylphenyl)benzamide
✍ Scribed by Zhou, Bin ;Zheng, Peng-Wu
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 604 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Molecules of the title compound, C 15 H 14 ClNO, are linked into chains along the c axis by intermolecular N-HÁ Á ÁO hydrogen bonds. The xylene and chlorobenzene rings deviate from the amide plane [C( O)-N] by 77.8 (1) and 29.7 (1) , respectively.
📜 SIMILAR VOLUMES
The molecules of the title compound, C 14 H 15 NO 2 S, are linked into centrosymmetric dimers via N-HÁ Á ÁO hydrogen bonds. The packing is influenced bystacking interactions [centroid-to-centroid separation = 3.780 (5) A ˚].
The molecular conformation of the title compound, C~14~H~14~N~2~O~4~S, is stabilized by an N—H...O hydrogen bond. The packing is influenced by π–π stacking interactions between nitrophenyl rings [centroid-to-centroid separation 3.744 (13) Å].
Single-crystal X-ray study T = 273 K Mean '(C±C) = 0.003 A Ê R factor = 0.040 wR factor = 0.112 Data-to-parameter ratio = 17.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C~23~H~19~ClN~2~O~2~, has been obtained by the reaction of (__Z__)-4-(4-chlorobenzylidene)-2-phenyloxazol-5(4__H__)-one and benzylamide. The molecules are connected by two N—H...O intermolecular hydrogen bonds to form helicoidal chains running parallel to the __c__ axis.