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(4-Carboxynaphthalene-1-carboxyl­ato)bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol]zinc(II) 4-carboxynaphthalene-1-carboxyl­ate dihydrate

✍ Scribed by Wang, Qing-Wei ;Yu, Zhi-Xin ;Meng, Qing-Long ;Zhao, Xiao-Hong


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
168 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the title compound, [Zn~2~(C~8~H~4~O~4~)Cl~2~(C~19~H~12~N~4~)~2~(H~2~O)~2~] or [Zn~2~(BDC)Cl~2~(__L__)~2~(H~2~O)~2~] (where BDC is benzene-1,4-dicarboxylate and __L__ is 2-phenyl-1__H__-1,3,7,8,-tetraaza-cyclopenta[__l__]phenanthrene), the two Zn^II^ atoms are bridged by the BDC ligand to form a

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In the title compound, [Zn(1,3-BDC)(L)] n , where 1,3-BDC is the 1,3-benzenedicarboxylate dianion (C 8 H 4 O 4 2À ) and L is 2phenyl-1H-1,3,7,8,-tetraazacyclopenta[l]phenanthrene (C 19 H 12 N 4 ), each Zn II atom is five-coordinated by two N atoms from one L ligand, and three O atoms from three 1,3-

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In the title complex, [Mn~2~(C~8~H~4~O~4~)~2~(C~19~H~12~N~4~O)~2~]~__n__~, the Mn^II^ atom is six-coordinated by two N atoms from the substituted phenanthroline ligand and four O atoms from three different benzene-1,3-dicarboxylate (1,3-BDC) ligands. Adjacent Mn^II^ atoms are bridged by the 1,3-BDC