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Poly[[(2-phenyl-1H-1,3,7,8,-tetra­azacyclo­penta­[l]­phenanthrene)zinc(II)]-μ3-1,3-benzene­dicarboxyl­ato]

✍ Scribed by Lin, Xian-Feng ;Sun, Jun ;Yu, Zhi-Xin ;Zhao, Xiao-Hong

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
220 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Zn(1,3-BDC)(L)] n , where 1,3-BDC is the 1,3-benzenedicarboxylate dianion (C 8 H 4 O 4 2À ) and L is 2phenyl-1H-1,3,7,8,-tetraazacyclopenta[l]phenanthrene (C 19 H 12 N 4 ), each Zn II atom is five-coordinated by two N atoms from one L ligand, and three O atoms from three 1,3-BDC anions, in a distorted square-based pyramidal geometry. The Zn II atoms are bridged by the 1,3-BDC ligands to form a double-chain structure. N-HÁ Á ÁO hydrogen bonds complete the structure.

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In the title compound, [Mn(C 6 H 8 O 4 )(C 19 H 12 N 4 ) 2 ]Á2H 2 O, the Mn II atom is six-coordinated by four N atoms from two bidentate phenanthrene ligands, and two carboxylate O atoms from a bidentate adipate ligand to result in a distorted MnO 2 N 4 octahedron. Aromaticstacking interactions bet

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In the title complex, [Mn~2~(C~8~H~4~O~4~)~2~(C~19~H~12~N~4~O)~2~]~__n__~, the Mn^II^ atom is six-coordinated by two N atoms from the substituted phenanthroline ligand and four O atoms from three different benzene-1,3-dicarboxylate (1,3-BDC) ligands. Adjacent Mn^II^ atoms are bridged by the 1,3-BDC