{N, prop-2-enylidene]ethylenediamine-2 N,N'}iodido(triphenylphosphane-P)copper(I)
[4-Bromo- N -(pyridin-2-ylmethylidene)aniline-κ 2N , N ′]iodido(triphenylphosphane-κ P )copper(I)
✍ Scribed by Khalaji, Aliakbar Dehno; Bahramian, Bahram; Jafari, Khadijeh; Fejfarová, Karla; Dušek, Michal
- Book ID
- 124169122
- Publisher
- International Union of Crystallography
- Year
- 2012
- Tongue
- English
- Weight
- 369 KB
- Volume
- 68
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.008 A Ê Disorder in main residue R factor = 0.057 wR factor = 0.134 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Tetrakis(2,2 0 0 0 -bipyridine)-1j 4 N,N 0 0 0 ;-4j 4 N,N 0 0 0 -hexa-l-iodido-1:2j 4 I:I;-2:3j 4 I:I;3:4j 4 I:I-1,4-dicadmium(II)-2,3-disilver(I)
The Cu I centre in the title compound, [Cu(C 14 H 14 N 2 )-(C 18 H 15 P) 2 ]ClO 4 , is covalently bonded to the P atoms of two triphenylphosphine ligands and to two N atoms of the Schiff base in a tetrahedral geometry.
In the structure of the title complex, [CuI(C 12 H 8 N 2 )-{Ph 2 PCH 2 CH 2 P(O)Ph 2 }]ÁCH 2 Cl 2 , the coordination polyhedron with copper as the central atom has a distorted tetrahedral geometry formed by two N atoms from 1,10phenanthroline, one iodide anion and one P atom from 1-(diphenylphosphin