✦ LIBER ✦

4-Benzylidene-2-methyl-11-phenyl-1,2,3,4,11,11a-hexahydropyrido[3,4-c][1,5]benzothiazepine

✍ Scribed by Athimoolam, S. ;Kumar, R. Ranjith ;Kannan, R. Sayee ;Sridhar, B. ;Bahadur, S. Asath

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 659 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807049598

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, C~26~H~24~N~2~S, the six- and seven-membered heterocyclic rings adopt half-chair and near-boat conformations, respectively. The molecular conformation is influenced by two weak intramolecular C—H...N interactions. The crystal structure is stablized by intermolecular C—H...N and C—H...π interactions.

📜 SIMILAR VOLUMES

(S)-2,3,5,10,11,11a-Hexahydro-1H-pyrrolo

(S)-2,3,5,10,11,11a-Hexahydro-1H-pyrrolo[2,1-c][1,4]benzodiazepine-3,11-dione

✍ Cheng, Mao-Sheng ;Ma, Chao ;Liu, Jing-Hong ;Sha, Yu ;Wang, Qing-He 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 627 KB

cis-1-Ethyl-4,4,10-trimethyl-2-tosyl-1,2

cis-1-Ethyl-4,4,10-trimethyl-2-tosyl-1,2,3,3a,4,11b-hexahydro-11H-pyrrolo[3,4-c]pyrano[5,6-c]quinolin-11-one

✍ Chinnakali, K. ;Sudha, D. ;Jayagopi, M. ;Raghunathan, R. ;Fun, Hoong-Kun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 741 KB

The molecule of the title compound, C~26~H~30~N~2~O~4~S, adopts a folded conformation, with the sulfonyl-bound benzene ring lying over the pyridinone ring [centroid-to-centroid distance = 3.893 (1) Å], forming a dihedral angle of 23.87 (5)°. The pyrrolidine ring adopts a twist conformation and the d

trans-1-Ethyl-4,4,10-trimethyl-2-tosyl-1

trans-1-Ethyl-4,4,10-trimethyl-2-tosyl-1,2,3,3a,4,11b-hexahydro-11H-pyrrolo[3,4-c]pyrano[5,6-c]quinolin-11-one

✍ Chinnakali, K. ;Sudha, D. ;Jayagobi, M. ;Raghunathan, R. ;Fun, Hoong-Kun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 785 KB

The asymmetric unit of the title compound, C 26 H 30 N 2 O 4 S, consists of two independent molecules, A and B, with similar conformations. In both molecules, the pyrrolidine and dihydropyran rings adopt envelope conformations, and are trans-fused; the tosyl group is attached to the pyrrolidine ring

Mass spectrometric studies of tetrasubst

Mass spectrometric studies of tetrasubstituted 3a,4,5,11-tetrahydro-3H-1,2,4-triazolo[4,3-d][1,5]benzothiazepines

✍ Jiaxi Xu; Meiyu He; Sheng Jin 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 53 KB 👁 1 views

The mass spectrometric behaviour of seven tetrasubstituted 3a ,4,5,2,3d][1,5]benzothiazepines has been studied with the aid of mass-analysed ion kinetic energy spectrometry and exact mass measurements under electron impact ionization. All compounds show a tendency to eliminate a neutral substituted

Preparation of 5,10,11,11a-Tetrahydro-1H

Preparation of 5,10,11,11a-Tetrahydro-1H,3H-thiazolo[2,3-c]- and 5,10,11,11a-Tetrahydro-1H,3H-thiazolo[4,3-c][1,4]benzodiazepines.

✍ Alexey B. Dyatkin; Bruce E. Maryanoff 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 111 KB 👁 2 views

2,3,4,5-Tetrahydro- and 2,3,4,5,11,11a-H

2,3,4,5-Tetrahydro- and 2,3,4,5,11,11a-Hexahydro-1H-[1,4]diazepino[1,7-a]indoles: New Templates for 5-HT2C Agonists.

✍ Michael D. Ennis; et al. et al. 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 121 KB 👁 1 views