4-Benzyl-3-(thiophen-2-yl)-4,5-dihydro-1 H -1,2,4-triazole-5-thione
✍ Scribed by Al-Shehri, Mona M.; El-Emam, Ali A.; El-Brollosy, Nasser R.; Ng, Seik Weng; Tiekink, Edward R. T.
- Book ID
- 125426578
- Publisher
- International Union of Crystallography
- Year
- 2013
- Tongue
- English
- Weight
- 505 KB
- Volume
- 69
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The acyclic C=N double bond of the title compound, C~10~H~10~N~4~S, is __trans__ configured. The molecule is almost planar. The angle between the two rings is just 10.25 (7)°. The crystal packing is stabilized by N—H...S hydrogen bonds and π–π interactions.
In the title compound, C 12 H 11 N 7 OS, the dihedral angles made by the thione-substituted triazole ring with the other triazole ring and the benzene ring are 71.56 (2) and 47.89 (3) , respectively. Inter-and intramolcular hydrogen-bond interactions stabilize the structure.
In the title compound, C~12~H~10~N~8~O~2~S, the triazole and benzene rings make dihedral angles of 72.16 (2) and 7.39 (3)°, respectively, with the thione-substituted triazole ring. In the crystal structure, intermolecular N—H...N hydrogen bonds link the molecules into chains running in the [101] dir