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4-Acetamido-N-(3-amino-1,2,4-triazol-1-yl)benzenesulfonamide

✍ Scribed by Juan, Fu ;Chuan-Fang, Zhu ;Yu-Ting, Sun ;Bo, Hu


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
664 KB
Volume
63
Category
Article
ISSN
1600-5368

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4-Amino-3-(1,2,4-triazol-1-yl)-1H-1,2,4-
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In the molecule of the title compound, C 5 H 7 N 7 S, the essentially planar triazole ring and the 4-amino-5-mercapto-1,2,4-triazole moiety make a dihedral angle of 70.97 (5) . In the crystal structure, weak intermolecular N-HÁ Á ÁN and N-HÁ Á ÁS hydrogen bonds stabilize the packing.

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In the title compound, C 18 H 20 N 4 O 2 , the triazole ring is twisted with respect to the two benzene rings with dihedral angles of 71.5 (3) and 67.3 (3) . N-HÁ Á ÁN hydrogen bonding occurs between neighboring molecules.

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The title compound, C 20 H 14 N 12 S 2 , was synthesized by the reaction of 3-hydrazino-1H-1,2,4-triazole with phenyl isocyanate in benzene and by ring closure in an alkaline medium. Intermolecular N-HÁ Á ÁN hydrogen bonds are observed and these form a five-membered ring.