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39K NMR study of potassium naphthalenide solutions

✍ Scribed by Maria Sokói; Janusz Grobelny; Marek Kowalczuk


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
576 KB
Volume
29
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

Potassium naphthalenide solutions in tetrahydrofuran were studied by means of ^39^K NMR spectroscopy. The effect of temperature, concentration and potassium cation complexation on paramagnetic shift and relaxation behaviour was demonstrated and is discussed. An attempt was made to assess the contributions due to the various relaxation mechanisms operating at different temperatures in the systems studied.


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