The title compound, C 22 H 20 N 2 O 3 , was synthesized by the reaction of 4-methoxybenzaldehyde, 7-methoxy-2-tetralone and malononitrile in the presence of triethylbenzylammonium chloride in an aqueous medium. X-ray analysis reveals that the pyran ring and the fused six-membered ring adopt boat and
3,9-Dimethoxy-6a,11a-dihydro-6H-benzo[4,5]furo[3,2-c]chromene-4,10-diol monohydrate
✍ Scribed by Aree, Thammarat ;Tip-pyang, Santi ;Paramapojn, Sompol ;Chaichit, Narongsak
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 319 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 218 K Mean '(C±C) = 0.003 A Ê R factor = 0.038 wR factor = 0.095 Data-to-parameter ratio = 18.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 183 K Mean '(C±C) = 0.003 A Ê R factor = 0.035 wR factor = 0.082 Data-to-parameter ratio = 12.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The structure of the title compound, C 13 H 16 O 4 , comprises a non-planar chiral molecule where the cyclohexene double bond is distinctly shorter [1.335 (2) A ˚] than the neighbouring C-C single bonds (>1.4 A ˚).