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(3,6-Dibromo-9H-carbazol-9-yl)(phen­yl)methanone

✍ Scribed by Duan, Xue-Min ;Xie, Wei-Sheng ;Huang, Peng-Mian ;Li, Jiang-Sheng ;Zheng, Peng-Wu

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
89 KB
Volume
62
Category
Article
ISSN
1600-5368

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3,6-Dibromo-9-eth­yl-9H-carbazole
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The title compound, C 14 H 11 Br 2 N, was synthesized by Nalkylation of bromoethane with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar and makes a dihedral angle of 94.7 (3) with the plane formed by the ethyl C and carbazole N atoms.

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The title compound, C 18 H 12 Br 2 N 2 , was synthesized by Nalkylation of 4-chloromethylpyridine with 3,6-dibromo-9Hcarbazole. The carbazole ring system is essentially planar, with a mean deviation of 0.012 A ˚, and makes a dihedral angle of 83.2 (8) with the plane of the pyridine ring. In the crys

9-(4-Nitro­phen­yl)-9H-carbazole
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In the title compound, C 18 H 12 N 2 O 2 , the carbazole ring system is essentially planar and makes a dihedral angle of 53.08 (4) with the plane of the nitrobenzene ring. In the crystal structure, inversion-related molecules form a C-HÁ Á ÁO hydrogen-bonded dimer.

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The title molecule, C~26~H~18~BrN, adopts the __Z__ configuration and shows normal values of bond lengths and angles. The crystal packing is stabilized by van der Waals forces.