345. The separation of polar and steric effects. Part I. The kinetics of the reaction of ortho-substituted benzoic acids with diazodiphenylmethane
✍ Scribed by Chapman, N. B. ;Shorter, J. ;Utley, J. H. P.
- Book ID
- 115472881
- Publisher
- The Royal Society of Chemistry
- Year
- 1962
- Weight
- 845 KB
- Category
- Article
- ISSN
- 0368-1769
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## Abstract The rate constants for the reaction of 2‐methyl‐cyclohex‐1‐enylcarboxylic, 2‐phenylcyclohex‐1‐enylcarboxylic, and 2‐methylbenzoic and 2‐phenylbenzoic acids with diazodiphenyl‐methane were determined in 14 various solvents at 30°C. To explain the kinetic results through solvent effects,
## Abstract The rate constants for the reaction of different cycloalkenylcarboxylic, cycloalkenylacetic acids, and phenylacetic acid with diazodiphenylmethane were determined in 12 aprotic solvents at 30°C. In order to explain the kinetic results through solvent effects, the second‐order rate const