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3,4-Homoadamantadiene: Generation and Regioselective [2+2] Cycloaddition of a Novel Tricyclic Bridgehead Allene

โœ Scribed by Ogawa, Kohei; Okazaki, Takao; Kinoshita, Tomomi

Book ID
120406995
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
75 KB
Volume
68
Category
Article
ISSN
0022-3263

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Generation and [4+2] cycloaddition of 1,6-methano[10]annulene-3,4-quinodimethane: a novel synthesis of dimethyl 1,6-methanobenzo[3,4-a][10]annulene-13,14-dicarboxylate
โœ Shigeyasu Kuroda; Mitsunori Oda; Shengli Zuo; Kimiko Kanayama; Shaheen I.M Shah; ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 77 KB

A new quinodimethane, 1,6-methano[10]annulene-3,4-quinodimethane (1), was generated and trapped by the Diels-Alder reactions with various dienophiles to provide 1,6-methano[10]annelenes 3 fused with a six-membered ring at the 3,4-positions, one of which was derived to a benzene ring analogue 4.