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[3.3.2]- and [3.3.3]Propellanes in Reactions with Oxidizing Electrophiles

✍ Scribed by T. E. Shubina; P. A. Gunchenko; T. S. Vigovskaya; P. R. Schreiner; A. G. Yurchenko; A. A. Fokin


Book ID
110396281
Publisher
Springer
Year
2002
Tongue
English
Weight
110 KB
Volume
38
Category
Article
ISSN
0040-5760

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πŸ“œ SIMILAR VOLUMES


Propellanes. Part LXXVIII. Preparation o
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## Abstract 3,7,10‐Tribenzyl‐3,7,10‐triaza[3.3.3]propellane (**4a**), 3,7‐dibenzyl‐10‐phenyl‐3,7,10‐triaza[3.3.3]propellane (**4c**), 3,7‐dibenzyl‐10‐(__p__‐tolyl)‐3,7,10‐triaza[3.3.3]propellane (**4b**), and 3‐oxa‐7,10‐diaza[3.3.3]propellane (**6**) have been prepared.

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The title compound was prepared by transammlar addition of a carbene to an exocyclic double bond. Rhodium acetate catalyzed decomposition of 2-diazo-&methylene-1,3-cyclooctanedione gave 1 quantitatively. We wish to report the first synthesis of the title compound, 1, and a new approach to propellan