The title compound was prepared by transammlar addition of a carbene to an exocyclic double bond. Rhodium acetate catalyzed decomposition of 2-diazo-&methylene-1,3-cyclooctanedione gave 1 quantitatively. We wish to report the first synthesis of the title compound, 1, and a new approach to propellan
✦ LIBER ✦
Interactions in 2,8,9-trifunctional [3.3.3] propellanes
✍ Scribed by Gleiter, Rolf ;Litterst, Edwin ;Drouin, Jacques
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1988
- Tongue
- English
- Weight
- 318 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0009-2940
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Single-crystal X-ray study T = 183 K Mean '(C±C) = 0.005 A Ê R factor = 0.067 wR factor = 0.166 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.