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31P NMR—structure correlations for phosphonocarboxylic acids and esters

✍ Scribed by Sabine Olagnon-Bourgeot; Francine Chastrette; Didier Wilhelm


Book ID
102952492
Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
571 KB
Volume
33
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

^31^P chemical shift‐structure correlations were established from methyl and ethyl esters of simple phosphonocarboxylic acids. The influence of solvent, acidity, function and neighbourhood of phosphorus was studied. The correlations could be extended and led to the identification of esters obtained when a series of phosphonocarboxylic acids were reacted with alcohols—reactions which were designed as models of cellulose cross‐linking by these acids.


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