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31P CP/MAS NMR of polycrystalline and immobilized phosphines and catalysts with fast sample spinning

✍ Scribed by S. Reinhard; J. Blümel


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
331 KB
Volume
41
Category
Article
ISSN
0749-1581

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✍ Massimiliano Arca; Francesco A. Devillanova; Alessandra Garau; Francesco Isaia; 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 97 KB

The reactions between triphenylphosphine sulfide (Ph 3 PS) and ICl in CCl 4 and IBr in CH 2 Cl 2 in 1 : 1 molar ratio give the solid adducts Ph 3 PS ´ICl (I) and Ph 3 PS ´IBr (II) whose structures have been solved by X-ray diffraction. Compounds I and II consist of discrete molecule units and featur