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31P and 27Al NMR study on the binding isomerism and isomerization equilibrium of aluminium-cyclopolyphosphate complexes in solution

✍ Scribed by Qi Feng; Hirohiko Waki; Genichiro Kura


Book ID
108429020
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
729 KB
Volume
10
Category
Article
ISSN
0277-5387

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The 'H and IBF NMR parameters of 5-fluoro-1,3-dioxan (1) dissolved in a number of solvent systems are interpreted on the basis of fast inversion between two chair conformations. In cyclohexane solution the two chair conformations are almost equally populated, whereas in more polar solvents, such as