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31P and 195 Pt NMR studies on fluxional η1-ligated 1,2,4-triphosphacyclopentadienyl palladium(II) and platinum(II) complexes

✍ Scribed by John F. Nixon; Gary J.D. Sillett


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
782 KB
Volume
461
Category
Article
ISSN
0022-328X

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Structural studies on chiral (π-Allyl)Pd
✍ Paul S. Pregosin; Renzo Salzmann 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 426 KB

## Abstract The chiral (π‐allyl)Pd(II) complex [Pd(η^3^CH~3~CHCHCH~2~)(__S, S__‐Chiraphos)]CF~3~SO~3~ was shown to exist in four isomeric forms (two diastereomeric and two geometric). Aspects of their three‐dimensional structures were elucidated using ^1^H, ^13^C and ^31^P one‐ and two‐dimensional