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3-(p-Nitro­benzyl)-1,3-thia­zolidine-2,4-dione

✍ Scribed by Yathirajan, Hemmige S. ;Rai, Kuriya M. Lokanatha ;Gaonkar, Santhosh L. ;Narasegowda, Rajenahally S. ;Prabhuswamy, Basappa ;Bolte, Michael

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
149 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 10 H 8 N 2 O 4 S, serves as a starting material for the synthesis of antihyperglycemic pharmaceuticals. The nearly planar thiazolidine-2,4-dione ring is almost perpendicular to the nitrophenyl ring.

📜 SIMILAR VOLUMES

3-(4-Chloro­benzyl)-5-(4-oxo-4H-chromen-
3-(4-Chloro­benzyl)-5-(4-oxo-4H-chromen-3-ylmethyl­ene)-1,3-thia­zolidine-2,4-dione
✍ Özgen, Özen ;Ceylan-Ünlüsoy, Meltem ;Bozdağ-Dündar, Oya ;Ertan, Rahmiye ;Kendi, 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 95 KB

In the title molecule, C 20 H 12 ClNO 4 S, the benzopyran ring system and the thiazolidine ring are planar. The dihedral angle between the chlorobenzyl and thiazolidine rings is 74.42 (8) . The crystal structure is stabilized by intermolecular C-HÁ Á ÁO hydrogen bonds.

2,2′-Bi-1,3-thia­zolidine
2,2′-Bi-1,3-thia­zolidine
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(Z)-2-(Dimethyl­amino)-5-(3,4,5-trimetho
(Z)-2-(Dimethyl­amino)-5-(3,4,5-trimethoxy­benzyl­idene)-1,3-thia­zolidin-4-one
✍ Low, John N. ;Cobo, Justo ;Gutiérrez, Alexander ;Insuasty, Braulio ;Glidewell, C 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 301 KB

In the title compound, C~15~H~18~N~2~O~4~S, there is a very wide C—C—C angle [130.72 (16)°] at the methine C atom linking the two rings. A single C—H...O hydrogen bond links pairs of molecules into dimers around a twofold axis.

(Z)-5-(3-Nitrobenzylidene)-1,3-thiazolid
(Z)-5-(3-Nitrobenzylidene)-1,3-thiazolidine-2,4-dione
✍ Sun, Hong-shun ;He, Wei ;Xu, Ye-ming ;Tang, Shi-gui ;Guo, Cheng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 580 KB

In the title compound, C~10~H~6~N~2~O~4~S, the benzene and thiazolidine rings are oriented at a dihedral angle of 8.8 (5)° to one another. In the crystal structure, intramolecular C—H...O and C—H...S hydrogen bonds are present; intermolecular N—H...O and C—H...O hydrogen bonds link the molecules int

2-(4-Chloro­phen­yl)-3-phenyl-1,3-thia­z
2-(4-Chloro­phen­yl)-3-phenyl-1,3-thia­zolidin-4-one
✍ Doreswamy, S. ;Jayalakshmi, K. ;Sridhar, M. A. ;Rangappa, K. S. ;Shashidhara Pra 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 362 KB

In the title compound, C~15~H~12~ClNOS, the thiazolidine ring adopts a twist conformation, with the S and adjacent C (bearing chlorophenyl) atom deviating by −0.140 (1) and 0.158 (2) Å, respectively, from the plane through the other three ring atoms.