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3-oxo-3-phosphapentopyranoses

✍ Scribed by Christopher J. R. Fookes; Michael J. Gallagher

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 444 KB
Volume: 7
Category: Article
ISSN: 1042-7163
DOI: 10.1002/(sici)1098-1071(199610)7:5<391::aid-hc17>3.0.co;2-l

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✦ Synopsis

Addition of methyl phosphinate to 2(R)-methoxy 3-oxapentanedial gives all eight possible diastereoisomeric 3-phosphapentopyranoses in very poor yield. Structures and stereochemistry are assigned on the basis of 'H, 318 NMR, and mass spectroscopy of their acetates.

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