3-methylthio-1,2-dithiolylium salts : Reaction with 4-hydroxy-6-methyl-2H-pyran-2-one and 4-hydroxycoumarin
✍ Scribed by E.G. Frandsen
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 392 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
## Abstract The synthesis and reactivity studies of 4‐hydroxy‐6‐methyl‐3‐(5‐phenyl‐2__E__,4__E__‐pentadien‐1‐oyl)‐2__H__‐pyran‐2‐one **2** with nucleophiles are reported. Reactions of **2** with hydrazine derivatives gave new pyrazole‐type com pounds while the reaction with __ortho__‐phenylenediami
## Abstract Phenylhydrazine or hydrazine react with 3‐acetyl‐4‐hydroxy‐6‐methyl‐2__H__‐pyran‐2‐one (1) to give 4‐acetoacetyl‐3‐methylpyrazolin‐5‐ones 4. The synthesis of bipyrazoles and pyrazoloisoxazoles from 4 are reported.
## Abstract 3‐(Bromoacetyl)‐4‐hydroxy‐6‐methyl‐2__H__‐pyran‐2‐one was synthesized by the reaction of dehydroacetic acid (DHAA) with bromine in glacial acetic acid. Novel heterocyclic products were synthesized from the reaction of bromo‐DHAA with alkanediamines, phenylhydrazines, __ortho__‐phenylene