3-Methylcyclopropene-3-carbonitrile as a new enophile of the Alder-ene reaction
β Scribed by Roman V. Ashirov; Svetlana A. Appolonova; Grigory A. Shamov; Vitaly V. Plemenkov
- Book ID
- 111730755
- Publisher
- Royal Society of Chemistry
- Year
- 2006
- Tongue
- English
- Weight
- 255 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0959-9436
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Most workers assume that the simple ene reaction' involves a concerted mechanism with the same syn-syn stereochemistry as the familiar Diels-Alder reaction. Actually, however, only those stepwise reactions involving initial hydrogen or proton transfer from the ene to the enophile are rigorously elim