𝔖 Bobbio Scriptorium
✦   LIBER   ✦

{3-Hydroxymethyl-1-[2-(3-methoxyphenyl)ethyl]-7-oxabicyclo[2.2.1]hept-5-en-2-yl}methanol

✍ Scribed by Wang, Ya-Wen ;Peng, Yu

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
602 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C~17~H~22~O~4~, is an oxabicyclo[2.2.1]hept-5-ene with two exo-oriented hydroxymethyl groups which are not parallel to each other. The molecules are linked to each other by hydrogen bonds, resulting in a supramolecular network. Intermolecular Oβ€”H...O hydrogen bonding is observed between the hydroxyl groups.

πŸ“œ SIMILAR VOLUMES

The Preparation of Optically Pure 7-Oxab
The Preparation of Optically Pure 7-Oxabicyclo [2.2.1]hept-2-ene Derivatives. The CD Spectrum of (+)-(1R)-7-Oxabicyclo [2.2.1]hept-5-en-2-one
✍ Eric Vieira; Pierre Vogel πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 German βš– 408 KB

Dedicated to Prof. Ch. Tamm on the occasion of his 60th birthday (12.4.83) ## Summary (-)-1-Camphanoyloxyacrylonitrile (= (-)-1 -cyanovinyl camphanate; 1) obtained from the commercially available ( -)-camphanoyl chloride and 2-0x0propiononitrile added to furan at 20" in the presence of CU(BF,)~.

2-Oxabicyclo[3.2.1]oct-7-yl-Kationen
2-Oxabicyclo[3.2.1]oct-7-yl-Kationen
✍ Kirmse, Wolfgang ;MΓΆnch, Dietmar πŸ“‚ Article πŸ“… 1992 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 213 KB
Regioselective Radical Additions to 7-Ox
Regioselective Radical Additions to 7-Oxabicyclo[2.2.1]hept-5-en-2-one
✍ Jean-Paul Vionnet; Kurt Schenk; Philippe Renaud πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 German βš– 658 KB

## Abstract Radical addition to 7‐oxabicylco[2.2.1]hept‐5‐en‐2‐one (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the