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3-H-isoxazolin-5-ones

โœ Scribed by Francesco De Sarlo; Giuliano Dini


Book ID
112121656
Publisher
Journal of Heterocyclic Chemistry
Year
1967
Tongue
English
Weight
316 KB
Volume
4
Category
Article
ISSN
0022-152X

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๐Ÿ“œ SIMILAR VOLUMES


Sigmatropic tautomerism between n-allyl-
โœ Yosuo Makisumi; Takashi Sasatani ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 178 KB

In continuation of our studies of 3,3-sigmatropic reactions, we have discovered the facile amino-Claisen rearrangement of the N-allyl-enamine system in pyrazolin-5-ones (1). Recent reports (2, 3,4) on the analogous examples of the amino-Claisen rearrangement prompt a preliminary report of our work o

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Alkylation of carbanions from isoxazolin
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Methyl acetoacetate and other B-keto esters can be converted into the corresponding isoxazolin-5-ones which can be metalated a to C-3. These anions are trapped by a range of electrophiles to produce 3-substituted isoxazolin-5-ones. Recently we required various B-amino a,B-unsaturated esters as

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