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3-(Dicyanomethylidene)-6,6-dimethylcyclohexa-1,4-diene

✍ Scribed by Kämpen, Jan ;Jones, Peter G. ;Bubenitschek, Peter ;Hopf, Henning

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
624 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C~11~H~10~N~2~, the six-membered ring is planar (r.m.s.d. 0.013 Å). Molecules are linked by weak C—H...N interactions into chains parallel to [201], which lie in planes parallel to (\overline{1}02).

📜 SIMILAR VOLUMES

Reactivity of 3,6-dimethoxy-3,6-dimethyl
Reactivity of 3,6-dimethoxy-3,6-dimethylcyclohexa-1,4-diene (Part 3). Regioselective α-arylation of ketones via their silyl enol ethers
✍ Francisco Alonso; Miguel Yus 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 339 KB

Abstmct: The reaction of 3,6-dimethary-3,6-dimethylcyclohea-l.4diene (I) with an ewess of dt@wtt silyl en01 ethers derived from ketones in the presence of zinc dichloride kads to the corresponding ketones regioselectively arylated at the (I position.

(Z)-3,6-Diethynyl-3,6-di­hydroxy­cyclo­h
(Z)-3,6-Diethynyl-3,6-di­hydroxy­cyclo­hexa-1,4-diene
✍ Bandyopadhyay, Arkasish ;Varghese, Babu ;Sankararaman, Sethuraman 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 280 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.059 wR factor = 0.154 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

1,6-Dioxo-cyclodeca-3,8-dien und 1,6-Dia
1,6-Dioxo-cyclodeca-3,8-dien und 1,6-Diamino-cyclodeca-3,8-dien. Cyclodecapolyene, 1. Mitteilung
✍ C. A. Grob; P. W. Schiess 📂 Article 📅 1960 🏛 John Wiley and Sons 🌐 German ⚖ 712 KB

## Abstract 1,6‐Dioxo‐cyclodeca‐3,8‐diene (4) and the __cis__ and __trans__ forms of 1,6‐diamino‐cyclodeca‐3,8‐diene (7) have been synthesized from naphthalene via isotetralin (1). No transannular reaction was observed during the reduction of the dioxime of (4) to the diamine (7).