𝔖 Bobbio Scriptorium
✦   LIBER   ✦

3-Cyano-N-methyl­pyridinium bromide

✍ Scribed by Mague, Joel T. ;Ivie, Ryan M. ;Hartsock, Robert W. ;Koplitz, Lynn Vogel ;Spulak, Mary


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
124 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


ÁBr À , forms a layered solid with each cation forming three strong and one weaker C-HÁ Á ÁBr hydrogen bonds within the layer. All atoms except two of the methyl H atoms lie on a mirror plane.

Experimental

An aqueous solution of 3-cyano-N-methylpyridinium iodide (Koplitz et al., 2003) was passed down a column of polymer-supported bromide ion exchange resin (Aldrich catalogue No. 51,376-8) and the


📜 SIMILAR VOLUMES


N-n-Butyl­pyridinium bromide
✍ Ji, Jin-Xiu ;Xu, Bin ;Liu, Shan ;Wang, Jin-Tang 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 238 KB

The title compound, C 9 H 14 N + ÁBr À , was synthesized by the reaction of pyridine and n-butyl bromide. The crystal packing is stabilized by intermolecular C-HÁ Á ÁBr hydrogen bonds.

1-[(2,4-Di­chloro­benzoyl)­methyl]-4-(N,
✍ Sundar, T. V. ;Parthasarathi, V. ;Sarkunam, K. ;Nallu, M. ;Walfort, B. ;Lang, H. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 260 KB

In the title compound, C 15 H 15 Cl 2 N 2 O + ÁBr À , the angle between the least-squares planes of the dichlorophenyl moiety and the pyridine ring is 20.23 (9) . The molecular packing is mainly in¯uenced by intermolecular CÐHÁ Á ÁBr hydrogen-bond interactions. The molecules form an extended chain a

2-Amino-(1-methyl­phen­yl)pyridinium bro
✍ Seethalakshmi, T. ;Venkatesan, P. ;Butcher, Ray J. ;Nallu, M. ;Kaliannan, P. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 268 KB
4-[N,N-Bis(2-cyano­ethyl)­amino]­pyridin
✍ Geng, Jin-Long ;Ni, Jun ;Liu, Rui ;Chen, Hui-Lan ;Wang, Zhi-Lin 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 179 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.049 wR factor = 0.118 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.