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3- and 3,4-Bis(2-cyanoethylsulfanyl)thiophenes as Building Blocks for Functionalized Thiophene-Based π-Conjugated Systems

✍ Scribed by Blanchard, Philippe; Jousselme, Bruno; Frère, Pierre; Roncali, Jean

Book ID
121709131
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
59 KB
Volume
67
Category
Article
ISSN
0022-3263

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Strong π-electron donors based on a self
Strong π-electron donors based on a self-rigidified 2,2′-bi(3,4-ethylenedioxy)thiophene–tetrathiafulvalene hybrid π-conjugated system
✍ Philippe Leriche; Mathieu Turbiez; Vincent Monroche; Pierre Frère; Philippe Blan 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 281 KB

Strong p-donors based on the association of TTF and 2,2%-bi(3,4-ethylenedioxy)thiophene conjugating unit have been synthesised; optical and an X-ray data show that intramolecular interactions lead to full rigidification of the conjugated system.