(3-Aminopyridine-κN1)(saccharinato-κN)silver(I)
✍ Scribed by Yilmaz, Veysel T. ;Hamamci, Sevim ;Kazak, Canan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 282 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.037 wR factor = 0.098 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.011 A Ê Disorder in solvent or counterion R factor = 0.055 wR factor = 0.174 Data-to-parameter ratio = 11.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The Ag I atom in the title compound, [Ag(C 5 H 6 N 2 ) 2 ] 2 -(C 8 H 4 O 4 )Á10H 2 O, shows linear coordination. The cation and centrosymmetric anion interact indirectly via the noncoordinated water molecules, to furnish a tightly held threedimensional structure.
The title compound, [Ag(C~7~H~8~NO~3~S)(C~2~H~3~N)(C~18~H~15~P)(H~2~O)]·0.5H~2~O, has a mononuclear structure in which the Ag^I^ ion is four-coordinated by the N atoms from a 3-amino-4-methylbenzenesulfonate anion and an acetonitrile molecule, one P atom from a triphenylphosphine ligand and one O at