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3-(2-Chloro-4-hydroxy­phen­yl)-1-thio­isocoumarin

✍ Scribed by Saeed, Aamer ;Ritch, Jamie S. ;Parvez, Masood


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
224 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The structure of the title compound, C 15 H 9 ClO 2 S, has a thioisocoumarin unit and a substituted phenyl group that are twisted at a dihedral angle of 33.40 ( 6) with respect to one another. In addition to weak O-HÁ Á ÁS interactions, C-HÁ Á ÁS/O/Cl-type interactions that stabilize the structure are also observed.


📜 SIMILAR VOLUMES


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In the structure of the title compound, C~15~H~13~ClN~2~OS, the dihedral angle between the two aromatic ring planes is 30.46 (8)°. Intermolecular N—H...S hydrogen bonds link the molecules into dimeric units which are stacked along [010].

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The title compound, C 14 H 9 Cl 3 N 2 OS, shows the typical geometric parameters of substituted thiourea derivatives. The crystal packing is characterized by N-HÁ Á ÁO and N-HÁ Á ÁS hydrogen bonds.