3-(2-Chloro-4-hydroxyphenyl)-1-thioisocoumarin
✍ Scribed by Saeed, Aamer ;Ritch, Jamie S. ;Parvez, Masood
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 224 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The structure of the title compound, C 15 H 9 ClO 2 S, has a thioisocoumarin unit and a substituted phenyl group that are twisted at a dihedral angle of 33.40 ( 6) with respect to one another. In addition to weak O-HÁ Á ÁS interactions, C-HÁ Á ÁS/O/Cl-type interactions that stabilize the structure are also observed.
📜 SIMILAR VOLUMES
In the title compound, C 14 H 10 Cl 2 N 2 OS, the geometric parameters do not show unusual features. The thiocarbonyl and carbonyl groups are almost coplanar with the chlorophenyl ring, as reflected by the torsion angles of 0.7 (3) and À5.8 (3) , respectively. The structure exhibits inter-and intram
The title compound, C 15 H 11 ClO 2 , is almost planar and adopts an E configuration. The dihedral angle between the two benzene rings is 10.76 ( 6) . An intramolecular O-HÁ Á ÁO hydrogen bond generates an S(6) ring motif. Molecules are arranged in layers approximately parallel to the (204) plane an
In the structure of the title compound, C~15~H~13~ClN~2~OS, the dihedral angle between the two aromatic ring planes is 30.46 (8)°. Intermolecular N—H...S hydrogen bonds link the molecules into dimeric units which are stacked along [010].
The title compound, C 14 H 9 Cl 3 N 2 OS, shows the typical geometric parameters of substituted thiourea derivatives. The crystal packing is characterized by N-HÁ Á ÁO and N-HÁ Á ÁS hydrogen bonds.