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(2SR,5SR,6SR)-Ethyl 5-[(4-chlorophenyl)sulfanyl]-2,6-bis(4-fluorophenyl)-4-hydroxy-1,2,5,6-tetrahydropyridine-3-carboxylate

✍ Scribed by Suresh, J. ;Kumar, R. Suresh ;Perumal, S. ;Natarajan, S.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
150 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C 26 H 22 ClF 2 NO 3 S, a polysubstituted piperidine enol, the tetrahydropyridine ring adopts a halfchair conformation. The crystal structure is stabilized by van der Waals and weak C-HÁ Á Á interactions. An intramolecular O-HÁ Á ÁS interaction generates an S(5) graph-set motif.

📜 SIMILAR VOLUMES

(2RS,5SR,6SR)-Ethyl 2,6-bis­(4-fluoro­ph
(2RS,5SR,6SR)-Ethyl 2,6-bis­(4-fluoro­phen­yl)-4-hydr­oxy-5-phenyl­sulfanyl-1,2,5,6-tetra­hydro­pyridine-3-carboxyl­ate
✍ Suresh, J. ;Kumar, R. Suresh ;Perumal, S. ;Natarajan, S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 280 KB

The title compound, C~26~H~23~F~2~NO~3~S, a polysubstituted piperidine enol, adopts a twisted half-chair conformation. The crystal structure is stabilized by N—H...F, C—H...O and weak C—H...π interactions. An intramolecular O—H...S interaction generates an __S__(5) graph-set motif.

ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis and Alkylation of N-Methylmorpholinium 4,5-trans-4-(2-Chlorophenyl)-3-cyano-6-hydroxy-5- (2-thenoyl)-6-trifluoromethyl-1,4,5,6-tetrahydropyridine-2-thiolate. Molecular and Crystal Structure of 4,5-trans-4-(2-Chlorophenyl)-3-cyano-6-hydroxy-2-methallylthio-5- (2-thenoyl)-6-trifluoromethyl-1,4,5,6-tetrahydropyridine.
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Ethyl 4-(4-hydroxy-3-methoxyphenyl)-6-methyl-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate
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In the title compound, C 15 H 18 N 2 O 4 S, the packing is consolidated by an intra/intermolecular bifurcated O-HÁ Á Á(O,O) and intermolecular N-HÁ Á ÁS hydrogen bonds. The tetrahydropyrimidin-2-one ring is twisted. ## Related literature For background, see: Kappe (1993). ## Experimental Cryst

ChemInform Abstract: Synthesis and Prope
ChemInform Abstract: Synthesis and Properties of Ammonium 5-Benzoyl-4- (2-chlorophenyl) -3-cyano-6-hydroxy-6-phenyl-1,4,5,6-tetrahydropyridine-2-thiolates.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

(2RS,5SR)-2,5-Diferrocenyl-1,6-di­benzoy
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The title compound, C 38 H 34 Fe 2 O 2 S 2 , is a novel disul®de. The SÐS bond distance is 2.0189 (11) A Ê . There are two chiral C atoms in the molecule, with relative stereochemistry RS and SR. Pairs of molecules form centrosymmetric dimers through weak CÐHÁ Á ÁS interactions which are, in turn, l