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2J(29SiO29Si) coupling constants in oligosiloxanes

✍ Scribed by Milan Kurfürst; Jan Schraml

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
113 KB
Volume
45
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The absolute values of spin–spin couplings between ^29^Si nuclei in siloxanes, ^2^J(^29^SiO^29^Si), were determined. The couplings are small and cover a narrow range of values (0–5 Hz). The coupling constants depend on the branching or on the number of electronegative substituents on the SiOSi moiety. Copyright © 2007 John Wiley & Sons, Ltd.

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