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Study of 1H29Si coupling constants in triethoxysilanes and silatranes by multiple quantum NMR

✍ Scribed by E. Liepinš; I. Birǧele; P. Tomsons; E. Lukevics

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
146 KB
Volume
23
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^29^Si^1^H coupling constants across two and three bonds in silatranes and model triethoxysilanes were measured from ^1^H spectra by multiple quantum NMR. There was an increase in the ^29^SiOCH coupling in the equatorial position and a decrease in that in the axial position of the silicon trigonal bipyramid compared with the tetracoordinated silicon.

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