29Si NMR Experiments in Solutions of Organosilicon Compounds
β Scribed by Jan Schraml
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 55 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract A new pulse sequence, 2D INEPTβPANACEA, that allows parallel acquisition of 2D ^29^Siο£Ώ^29^Si INADEQUATE and 2D ^29^Siο£Ώ^1^H HMBC spectra and also provides the 1D ^29^Si NMR spectrum has been designed for use with organosilicon compounds and tested using a mixture of OHβterminated polydim
Trisilylamines (1), (2), (3), (Me 3 Si) 3 N [Me 2 (HCyC)Si] 3 N [ M e 2 (HCyC)Si] 2 NSiMe 2 Br (4) and (5) were studied by 13C, 15N and 29Si NMR spectroscopy. The [Me 2 (Br)Si] 2 NSiMe 2 CyCH [Me 2 (Br)Si] 3 N trends in their chemical shifts, in particular of d15N, coupling constants 1J(29Si, 13C)
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v