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29Si chemical shifts and additivity in pertrimethylsilylated O-methyl, O-benzyl, O-benzoyl and O-acetyl methyl β-D-xylopyranosides

✍ Scribed by J. Schraml; E. Petráková; O. Pihar; J. Hirsch; V. Chvalovský


Book ID
102555726
Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
366 KB
Volume
21
Category
Article
ISSN
0749-1581

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✍ J. Schraml; E. Petráková; J. Hirsch 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 503 KB

Si and ''C NMR spectra of all possible pertrimethylsilylated p-D-xylopyranosyl-substituted methyl 4-0-p-Dxylopyranosyl-p-D-xylopyranosides are assigned by heteronuclear 'H-X 2D NMR chemical shift correlation experiments, where X = C or Si. It is shown that the 29Si NMR spectra can be used for identi