Molecular and crystal structure of β-methyl-2,3-di-O-acetyl-4-O-trityl-D-xylopyranoside
✍ Scribed by L. G. Vorontsova; M. O. Dekaprilevich; O. S. Chizhov
- Book ID
- 112443297
- Publisher
- Springer
- Year
- 1985
- Tongue
- English
- Weight
- 376 KB
- Volume
- 34
- Category
- Article
- ISSN
- 1573-9171
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## Crystals of the tetrasaccharide, (2,3,4,6-tetra-0acetyl-fi-D-ghxopyranosyl~-(1 + 3)-[2,3,4,6-tetra-O-acetyI+LD-gIucopyranosyI-(1 --t 6)]-(2,4-di-0-acetyl-g\_D-glucopyranosyl)-1 --) 3)-1,2,4,6-tetrad-acetyl$?-n-ghicopyranose, belong to tge monoclinic system, space group P2,, with a = 12.709(4),
Acylated ]3-o-xylopyranose derivatives are known to exist as a mixture of the 1C 4 and 4C I conformers in rapid equilibrium in solution [3]. Several conformations have also been reported for/3-D-xylopyranose derivatives in the solid state [4]. In the course of our study to investigate the functions