2,9-Bis(methoxymethyl)-1,3,8,10-tetrathiacyclotetradecane
✍ Scribed by Gültekin, Zeynep ;Bayrak, Hacer ;Frey, Wolfgang ;Hökelek, Tuncer
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 243 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 14 H 28 O 2 S 4 , possesses a crystallographically imposed inversion centre and has two methine C atoms linked to methoxymethyl functional groups. It is in the exodentate conformation, with the four S atoms lying on the edges of the `rectangular' macrocycle. The lone pairs of electrons on the S atoms point outwards from the macrocyclic cavity and the S atoms are bridged alternately by one-carbon and four-carbon moieties.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê Disorder in solvent or counterion R factor = 0.037 wR factor = 0.091 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.036 wR factor = 0.105 Data-to-parameter ratio = 17.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.003 A Ê R factor = 0.067 wR factor = 0.165 Data-to-parameter ratio = 12.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.